The other first-round pairings match Mark Trumbo, of the Baltimore Orioles, against rookie Corey Seager, of the Los Angeles Dodgers, and Robinson Cano, of the Seattle Mariners, against Giancarlo Stanton, of the Miami Marlins.
The brackets were determined by home run totals. Trumbo leads baseball with 26 home runs. Duvall has 22.
Duvall will be the eighth Red to compete in the derby. Frazier won the event as a Red last year at Great American Ball Park, becoming only the second player to win the derby at home, following Ryne Sandberg, of the Cubs, in 1990.
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